Arm-replaceable star-like nanogels: arm detachment and arm exchange reactions by dynamic covalent exchanges of alkoxyamine units
نویسندگان
چکیده
منابع مشابه
Reorganization of polymer structures based on dynamic covalent chemistry: polymer reactions by dynamic covalent exchanges of alkoxyamine units
The recent progress of research on polymer reactions utilizing dynamic covalent exchanges of alkoxyamine units—adducts of styryl and stable nitroxide radicals—is reviewed. The alkoxyamine derivatives derived from 2,2,6,6-tetramethylpiperidine-1-oxy (TEMPO, a stable free radical) are frequently utilized as unimolecular initiators for the nitroxide-mediated radical polymerizations. In the absence...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 2010
ISSN: 0032-3896,1349-0540
DOI: 10.1038/pj.2010.83